李中军教授——郑州大学化学与分子工程学院博士生导师

郑大考研网

李中军科研情况简介

个人基本情况：

李中军， 男，1963年3月出生， 1983年毕业于郑州大学化学系无机化学专业，获理学学士学位。1989年郑州大学化学系无机化学专业研究生毕业，获理学硕士学位。1998年9月中南大学有色冶金专业博士研究生毕业，获工学博士学位。现为郑州大学化学系教授，博士研究生指导教师，河南省学术技术带头人,河南省化学会常务理事。

研究方向：无机材料化学

主要围绕无机化合物光催化材料，羟基磷灰石-胶原复合生物材料及氧化铝、氧化锆和氧化钛等无机功能材料的制备、性能及相关应用开展研究。

主持承担及完成的主要课题：

1、“SOFC用稀土掺杂氧化锆基纳米功能材料的研究开发”， 河南省杰出人才创新基金，起止年月：2005-2007，项目编号： 0521001100，经费 30万元。

2. “羟基磷灰石-胶原复合生物材料的制备研究”，横向课题，起止年月：2006-2009，经费 10万元。

2、“给体-受体”型稀土发光纳米粒子的制备和荧光调控”，国家自然科学基金面上项目，起止年月：2010. -2012.，项目编号：20971111；经费35万元。

3、 “氧化铝纤维生产技术”，河南煤化集团横向合作项目。起止年月：2011-2013，经费 50万元。

已取得的研究成果：

近年来，主持完成多项省级及横向课题，公开发表学术论文70余篇，其中SCI、EI收录论文40篇，作为副主编出版《配合物化学 》、《化学 环境  社会》和《综合化学实验》学术著作3部。省级鉴定科研成果10项.，获奖3项，其中：

“氰化金钾生产及新工艺” 1997年获河南省科技进步二等奖；

“超细二氧化硅粉末制备新工艺” 2000年获河南省科技进步三等奖；

“铬渣无害化处理技术工业化研究” 2010年获河南省科技进步三等奖。

近期发表的主要论文：

1. Shen Xiaoqing, Du Yanjun, Zhou Yuanyuan, Wang Si, Liu Bin, Li Zhongjun.* Adsorption Properties of Phospho-Polypeptide on Synthetic Hydroxyapatite Biomaterials.   Applied Mechanics and Materials, 2012,130-134 ,1445-1447

2. Hong-Chang Yao*, Xue-Li Zhao, Xing Chen, Ji-Chao Wang, Qian-Qing Ge, Jian-She Wang, Zhong-Jun Li. “Processing and characterization of CoO and Sm2O3 codoped ceria solid solution electrolyte”. Journal of Power Sources ，2012, 205, 180-187

3.Yongyu Li, Jianshe Wang, Hongchang Yao, Liyun Dang, Zhongjun Li*, Efficient decomposition of organic compounds and reaction mechanism with BiOI photocatalyst under visible light irradiation,  J. Mol. Catal. A: Chem., 2011, 334, 116-122.

4.Yongyu Li, Jianshe Wang*, Hongchang Yao, Liyun Dang, Zhongjun Li*, Chemical etching preparation of BiOI/Bi2O3 heterostructures with enhanced photocatalytic activities, Catal. Commun., 2011, 12, 660-664.

5. Yongyu Li, Jianshe Wang, Bin Liu, Liyun Dang, Hongchang Yao, Zhongjun Li*.  “BiOI-sensitized TiO2 in phenol degradation: A novel efficient semiconductor sensitizer”. Chemical Physics Letters, 2011, 508, 102–106.

6.Yongyu Li, Hongchang Yao, Jianshe Wang, Ning Wang, Zhongjun Li*, Influence of the precipitation pH on the compositions and properties of Bi-based oxyiodide photocatalysts, Mater. Res. Bull., 2011, 46, 292-296.

7. Hong-Chang Yao*, Jian-She Wang, Dong-Ge Hu, Jing-Feng Li, Xiao-Rui Lu, Zhong-Jun Li*. “New approach to develop dense lanthanum silicate oxyapatite sintered ceramics with high conductivity”. Solid State Ionics 2010, 181, 41–47.

8..Jianshe Wang*, Yanxia Li, Qianqing Ge, Hongchang Yao, Zhongjun Li*, Preparation and luminescence of water soluble poly (N-vinyl-2-pyrrolidone)  /LaF3:Eu3+ nanocrystals, Appl. Surf. Sci.，2011, 257, 4100-4104.

9. Hong-Chang Yao*, Yu-Xin Zhang, Jia-Jia Liu, Yue-Li Li, Jian-She Wang, Zhong-Jun Li, Synthesis and characterization of Gd3+ and Nd3+ co-doped ceria by using citric acid–nitrate combustion method, Mater. Res. Bull., 2011, 46, 75-80.

10. Hong-Chang Yao, Xian-Wei Wang, Hao Dong, Rui-Rui Pei, Jian-She Wang, Zhong-Jun Li*，Synthesis and characteristics of nanocrystalline YSZ powder by polyethylene glycol assisted coprecipitation combined with azeotropic-distillation process and its electrical conductivity，Ceramics International， 2011，37，3153–3160

11. Xiao-qing Shen, Yuan-yuan Zhou, Xiao-ping Chen, Ming-sheng Tang, Zhong-jun Li*. Preparation and adsorption properties of phospho-L-glutamic acid on hydroxyapatite,     Surf. Interface Anal., 2011,43:1282-1285.

12. Si Wang, Xiao-Qing Shen, Hong-Chang Yao, Zhong-Jun Li*. Synthesis and Sintering of Pre-mullite Powders Obtained via Carbonate Precipitation.

Ceram. Int., 2010, 36, 761-766.

13. Liu Zhongyi, Sun Haijie, Wang Dongbin, Guo Wei, Zhou Xiaoli, Liu Shouchang, Li Zhongjun*. Selective Hydrogenation of Benzene to Cyclohexene over Ru-Zn Catalyst with Nanosized Zirconia as Dispersant.

Chin. J. Catal., 2010, 31, 150-152.

14. Liu Zhongyi, Sun Haijie, Wang Dongbin, Liu Shouchang, Li Zhongjun*. The Modifiable Character of a Novel Ru-Fe-B/ZrO2 Catalyst for Benzene Selective Hydrogenation to Cyclohexene.  Chin. J. Chem. 2010, 28, 1927-1934.

15. Li Zhang，Jianshe Wang，Hongchang Yao，Zhongjun Li*. Green photoluminescence of Tb3+ and Ce3+ doped mullite nanoparticles.

Mater. Lett. 2009, 63, 1175-1176.

16. Jianshe Wang, Weiran Miao, Yanxia Li, Hongchang Yao，Zhongjun Li*. Water-Soluble Ln3+-doped Calcium Fluoride Nanoparticles: Controlled Synthesis and Luminescence Properties. Mater. Lett., 2009, 63, 1794-1796.

17. Xiao-Qing Shen, Zhong-Jun Li, Ya-Li Niu, Hai-Bin Qiao. Thermal Behaviors and Decomposition Kinetics of a Ni(II) Complex with 2-Pyridinecarboxylic Acid.

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry.  2009, 39, 55-59.

18. Xiao-Qing Shen, Hong-Chang Yao, Rui Yang, Zhong-Jun Li, Hong-Yun Zhang, Ben-Lai Wu, Hong-Wei Hou   Synthesis, structure and thermal properties of      polynuclear complexes with a new multidentate ligand, N,N’-bis(5-ethyl-1,3,4-thiadiazol-2-yl)-2,6-pyridinedicarboxamide

                                     Polyhedron  2008, 27：203–209

19. Hong-Chang Yao, Miao-Miao Li, Li-Min Zheng, Zhong-Jun Li ，Structure and magnetism of a linear trimanganese (III, II, III) complex based on benzoate and Schiff-base ligands

J. Coord. Chem. 2008, 61：2814-2822

20. Hong-Chang Yao, Miao-Miao Li, Gao-Sheng Yang, Zhong-Jun Li & Yu Zhu Ketonization of methylene of bis(benzimidazol-2-yl)methane by molecular oxygen under the catalysis of cobalt(II) ion  

Inorg. Chim. Acta  2007, 360：3959–3964.

21. Xiao-Qing Shen, Hai-Bin Qiao, Zhong-Jun Li, Hong-Yun Zhang, et al. 3D coordination

polymer of copper (II)-potassium (I): crystal structure and thermal decomposition kinetics

Inorg. Chem. Acta  2006，359:642-648

22．Yunyin Niu, Zhongjun Li, Yinglin Song, Mingsheng Tang et al. Three-dimensional molecular network, [{Cu(dps)2(SO4)}3H2ODMF]n, and its different third-order NLO performance (dps = 4,4’-dipyridyl sulfide)   

J. Solid State Chem.  2006，179：4003-4010

23. Zhongjun Li, Xiaoqing Shen, Xun Feng, Peiyuan Wang, Zhishen Wu. Non-isothermal Kinetics Studies on the Thermal Decomposition of Zinc Hydroxide Carbonate.

Thermochimica Acta  2005, 438:102-106

24. Zhongjun Li, Peiyuan Wang, Zhishen Wu, Preparation of nanosized hydroxyapatite

particles at low temperatures.        J. Mater. Sci.  2005, 40:6589-6591

25. Feng Xun, Li Zhong-Jun, Wang Pei-Yuan, Zhou Yi-Feng, Preparation and gas-sensitivity of ultra-fine zinc-oxide powders from roasted zinc-blended,  

J. Mater. Sci.  2005，40:6597-6600

26. Xiao-Qing Shen, Zhong-Jun Li, Hong-Yun Zhang, Yi-Feng Zhou. Mechanism and Kinetics of Thermal Decomposition of 5-benzylsulfanyl-2-amino-1,3,4-thiadiazole.

Thermochimica Acta  2005, 428:77-81

27. Xiao-Qing Shen, Zhong-Jun Li, Hong-Yun Zhang,Hai-bin Qiao. Structure and thermal behaviors of organic crystals based on substituted 1,3,4-thiadiazoles.

                                  J. Phys. Chem. Solids.  2005, 66: 1755-1760  

28. Zhongjun Li, Xun Feng, Hongchang Yao. Ultrafine alumina powders derived from ammonium aluminum carbonate hydroxide.    J. Mater. Sci.  2004, 39: 2267-2269

29. Min Guan, Zu Qiang Bian, Yi Feng Zhou, Fu You Li, Zhong Jun Li, Chun Hui Huang.  High performance bule electroluminescent devices based on 2-(4-biphenylyl)-5-(4 carba -zole-9-yl) phenyl-1,3,4-oxadizazole.   Chem. Commun. 2003, (21): 2708-2709

30. Zhongjun Li, Xiaoqing Shen, Hongchang Yao, Jianjun Li. Preparation of ultrafine silica powders.                        J. Mater. Sci. Lett.  2002, 21:995－997

31. Zhongjun Li, Changrang Liu, Qinsheng Zhao. Effect of heat treatment on the pore structure properties of silica gel powders derived from water glass

J. Non-Cryst. Solids, 2000, 256:189-192