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樊耀亭
樊耀亭,男,汉族, 49年12月生,河南新密市人,中共党员, 工学博士,郑州大学化学系教授,博士生导师。
主要工作和教学经历:
1982年1月兰州大学化学系稀土化学专业研究生毕业,获理学硕士学位,同年回郑州大学化学系任教至今。1994年10月~1998年3月,大连理工大学化工学院攻读无机化工专业博士,获工学博士学位。2002年被河南省政府命名为河南省优秀专家。
近年来为本科生和研究生讲授的主要课程:中级无机化学、无机化学实验、稀土元素化学、配位化学、近代化学分离技术、废水生物处理技术。
学术兼职:
兰州大学兼职教授、兼职博导。河南省无机化学重点学科学术带头人,郑州大学应用化学学科学术带头人,郑州大学环境科学与工程研究中心主任。全国氢能专业委员会委员,河南省化学会常务理事,河南省环境学会理事;郑州市环保协会常务理事。《化学研究》和《河南化工》期刊编委。
主要研究成果:
2000年以来累计在国内外较有影响的学术期刊上发表学术论文69篇(其中英文SCI论文39篇,中文SCI、EI、SCIE和核心期刊论文22篇);有些论文发表在Chem.Commun.,Solid State Chemistry, Talanta, Polyhedron, J.Chem.Soc.Dalton Trans.,Molec.Struc.,Bioresource Technology ,Biomass & Bioenergy以及化学学报、无机化学学报、环境科学、太阳能学报、中国环境科学等刊物上;获得两项国家发明专利授权,连续三次主持国家自然科学基金项目、主持一项国家重点基础研究发展规划(科技部973计划)子课题。有2项教学成果和3项科研成果分别通过省教育厅和科技厅鉴定,其中1项教学成果2000年度获得河南省高校教学成果特等奖。
主要研究方向:
功能配位材料化学:本研究方向致力于设计合成具有微孔材料、光学材料及磁性材料功能的新型金属配位化合物或聚合物,通过对有机配体的结构设计、对功能配位基团的结构修饰,改变有机配体的配位环境,有针对性地合成、设计具有良好电磁功能或小分子吸附功能的配合物、配位聚合物或超分子配合物。测定配合物的结构,研究其组装机理,探索影响金属配合物电磁性质、吸附性质与配合物结构之间的内在关系、规律和机理研究不同不同功能配位基团对金属配聚物结构设计和性能的影响,寻找影响金属配合物选择性吸附催化、非线性光学性质及磁学性质的因素及其与结构的关系和规律,筛选出在某些材料领域具有优异性能的功能性配位化合物。
我们已系统合成了具有二位和三维结构的过渡金属的有机二磷酸系列配位聚合物,研究表明有些配聚物具有很好的三阶非线性光学性质和磁学性质,例如镉的三维配聚物[NH3CH(CH3)CH2NH3]2 Cd(II)2(edbbp)2?xH2O 的三阶非线性分子超极化率达到8.57×10-30esu,铜的二维聚合物 Cu4(aedp)2 (4,40-bpy)(H2O)4 在300K 的摩尔磁化系数达到 1.70 1.5 cm3 mol_1K。
生物能源技术:本研究方向以纤维素类生物质规模化生物制氢为目标,利用现代化学和生物技术的耦合,研究秸秆类生物质生物制氢过程中的关键化学和生物问题,揭示和解决影响及制约秸秆类生物质发酵产氢中的技术瓶颈及其发酵产氢的工程技术基础,形成可持续、稳定、规模化生物制氢过程的基本理论和技术。
附:2000年以来承担的主要项目及代表性研究成果:
承担的主要课题
①太阳能规模制氢的机理研究——生物质厌氧发酵生物制氢的研究,国家重点基础研究发展规划(973计划)项目子课题(No 2003CB214500,(6-2)), 29.1万; 2003.12-2008.12
② 活性基团构筑的新型金属有机磷酸配合物的研究(20471053),国家自然科学基金项目, 2005.1-2007.12
③ 具有纳米孔洞的高活性磷酰化氨基酸金属超分子配合物(No. 20171040), 国家自然科学基金项目, 2002.1-2004.12
④ 三角螺旋结构过度金属超分子功能配合物的研究(No.29871025), 国家自然科学基金项目, 1999.1-2001.12
代表性研究成果
1.发明专利
① 樊耀亭,侯红卫,任保增,天然厌氧产氢微生物的筛选方法,国家发明专利号:ZL 03126345.3(证书编号:251084)
② 樊耀亭,侯红卫,张高生,用农业固体废弃物生产氢气的方法,国家发明专利号:ZL 03126344.5(证书编号:219428)
③ 侯红卫,韩华云,樊耀亭等,氟康唑配位聚合物、制备方法及用途,申请号200410010159.8, 2004年,中国发明专利
2. 鉴定与获奖项目
① 清洁生物质能源——生物氢气的生产与开发,2002年河南省科技厅鉴定,第一完成人,No 2002-104
② 面向21世纪地方院校化学类专业培养目标、规格和课程方案的研究与实践,河南省教育厅2000年教学成果鉴定,第一完成人,No.2000-069
③ 面向21世纪化学类专业各门主干课程教学内容和体系的改革与实践,河南省教育厅2000年教学成果鉴定,第三完成人,No.2000-068
④ 面向21世纪地方院校化学类专业培养目标、规格和课程方案的研究与实践,第一完成人,2001年河南省高等教育省级教学成果特等奖,No.2001-00519
⑤ 面向21世纪化学类专业各门主干课程教学内容和体系的改革与实践,2001年郑州大学教学成果二等奖,第三完成人
3. 已发表的代表性学术论文
1. Yao-Ting Fan*, Ya-Hui Zhang, Shu-Fang Zhang, Hong-Wei Hou, Bao-Zeng Ren,Efficient conversion of wheat straw wastes into biohydrogen gas by cow dung compost, Bioresource Technology,2006,97:500?C505
2. Yao-TingFan* ,Gao- Sheng Zhang, Xin- Yong Guo, Yan Xing, Mao-Hong Fan,Biohydrogen-production from beer lees biomass by cow dung compost,Biomass and Bioenergy,2006,30:493?C496
3. De-Gang Ding, Ming-Cai Yin, Hui-Jie Lu, Yao-Ting Fan*, Hong-Wei Hou, Yu-Ting Wang,A novel copper diphosphonate complex Cu4(aedp)2(4,40-bpy) (H2O)4 with three-dimensional framework structure,Journal of Solid State Chemistry,2006,179 :747?C752
4. DONGXU XUE, MINGCAI YIN, YAOTING FAN*, AIXIN ZHU, HUIJIE LU and HONGWEI HOU,Synthesis and crystal structure of a new zinc diphosphonate,Journal of Coordination Chemistry,2005,58(16, 10):1449?C1454
5 .Yaoting Fan, Gang Li, Zifeng Li, Hongwei Hou, Hairong Mao, Synthesis, structure and third-order nonlinear optical properties of 1,3,5-triazine-based Zn(II) three-dimensional supramolecule, J. Molecular Structure, 2004,693,217-224
6. Y.T. Fan, Ch.L. Li, J.J.Lay, H.W. Hou, G..Sh. Zhang, Optimization of intial substrate and pH levels for germination of sporing hydrogen-producing anaerobes in cow dung compost, Bioresourse Technology, 2004;91:189-193.
7. Synthesis, crystal structures, and third- order nonlinear optical properties of two novel complexes of H4edbbp with Zn(II), Cd(II),J. Mol. Struct.,2004, 707,153?C160
8..Xiangru Meng, Bo Xiao, Yaoting Fan, Hongwei Hou ,Gang Li, Novel Cup-Like helical coordination Polymers:;synthesis,Crystal struvtures and thermsl properties, Inorg. Chim. Acta, 2004,357:1471-1477
9. Yao-Ting Fan* Dong-Xu Xue Gang Li Hong-Wei Hou Chen-Xia Du Hui-Jie Lu, Synthesis, crystal structures, and third-order nonlinear optical properties of two novel complexes of H4edbbp with Zn(II), Cd(II), J. Molecular Structure, 2004, 707 :153?C160
10. Yaoting Fan* Hairong Mao Huijie Lu Hongwei Hou, A new 2-D supramolecular compound assembled byyttrium(III) and 4-methyl-6-hydroxy pyrimidine(MHP): {[Y(H2O)8](MHP)2(NO3),Synth. React.Inorg. Met-org. Chem.,2003,33(1):99-101
11. Huijie Lu Jie Gao Yaoting Fan* Hongwei Hou , Synthesis , characterization and crystal structures of the coordination polymers [Cu(Ⅱ)(NO3)2(BBMB)] and [Mn(Ⅱ)Cl2(BBMB)2], J.Coor.Chem.,2003,53:1028-1032
12.Gang Li, Yinglin Song, Hongwei, Like Li Hou, Yaoting Fan, Yu Zhu, et al.,Synthesis ,crystal structures,and third-order nonlinear optical properties of a series of ferrocenyl organometallics ,Inorg. Chem. ,2003,42:913-920(SCI)
13.Gang Li, Hongwei Hou, Linke Li, Xiangru Meng, Yaoting Fan, Yu Zhu, Novel Pb(II), Zn(II), and Cd(II) coordination polymers constructed from ferrocenyl-substituted carboxylate and bipyridine-based ligands, Inorg. Chem. 2003,42, 4995-5004(SCI)
14.Hongwei Hou, Linke Li, Gang Li, Yaoting Fan and Yu Zhu “Self-assembly of a series of novel metal-organic compounds containing ferrocenecarboxylate components” ,Inorg. Chem. 2003, 42, 3501-3508. (SCI)
15.Xiangru Meng, Gang Li, Hongwei Hou, Huayun Han, Yaoting Fan, Yu Zhu, Chenxia Du, A series of novel metal-ferrocenedicarboxylae coordination polymers: crystal structures, magnetic and luminescence properties, J. Organomet. Chem. 2003, 679(2), 153-159(SCI)
16.Hongwei Hou, Gang Li, Yinglin Song, Yaoting Fan, Yu Zhu and Lu Zhu,Synthesis, crystal structures and third-order nonlinear optical properties of two novel ferrocenyl Schiff base complexes[Ag(L)2](NO3)×(MeOH)×(EtOH)and[HgI2(L)](L=1,2-Bis(ferrocenlylmethyleneamino)
ethane, Eur.J.Inorg.Chem.,2003, 2325-2332
17.Gang Li, Bingyi Chen, Linke Li, Hongwei Hou, Yu Zhu and Yaoting Fan,Synthesis, crystal structure and thermal properties of novel ferrocenecarboxylato-bridged Zn(II) dimmer [Zn2(m-OOCFc)4(3-PyCOOCH3)2]”, J. Coord. Chem., 2003, 56(10), 877-884.
18.Xiangru Meng, Yinglin Song, Hongwei Hou, Yaoting Fan, Gang Li, and Yu Zhu, Novel Pb and Zn Coordination Polymers: Synthesis, Molecular Structures, and Third-Order Nonlinear Optical Properties ,Inorg. Chem. 2003, 42, 1306-1315.
19.Linke Li , Bingyi Chen , Yinglin Song , Gang Li , Hongwei Hou ,*, Yaoting Fan ,Liwei Mi, Synthesis, crystal structure and third-order nonlinear optical properties of a novel coordination polymer [Cd(en)(NO3)2(4,4’-bpy)]n containing three kinds of ligands, Inorg. Chimi. Acta 2003,344: 95_101
20. Xiangru Meng, Yinglin Song, Hongwei Hou,*, Yaoting Fan, Gang Li, and Yu Zhu, Novel Pb and Zn Coordination Polymers: Synthesis, Molecular Structures, and Third-Order Nonlinear Optical Properties, Inorg. Chem., 2003, 42(41): 1306-1315
21.Hongwei Hou,* Gang Li, Linke Li, Yu Zhu, Xiangru Meng, and Yaoting Fan, Synthesis, Crystal Structures, and Magnetic Properties of Three Novel Ferrocenecarboxylato-Bridged Lanthanide Dimers, Inorg. Chem., 2003, 42(2):428-435
22. Zhenning Yan Yaoting Fan* Qiaoying Gao Huijie Lu HongweiHou, Tripodal compound1, 1,1-tris(N-ethyl-N-pheylamino -carboxyl methexymethyl) propane as an ionophore for alkali and alkaline earth metal cations-selective electrode, Talanta, 2002,57:81-88
23. Huijie Lu Yaoting Fan* et al.Studies on the synthesis and caton binding properties of tris(2-pyridylamino- carbonylmethoxymethyl)propane and tri(2pyridyl-amino-carbonylmethyl)amine,Synth. React.Inorg. Met-org. Chem.,2002,32(9):1537-1540
24. Gang Li Hongwei Hou* Yunyin Niu Yaoting Fan Zhishan Liu, Synthesis,crystal and structures and magnetic properties of helical double-stranded three-dimensional network [Co(NO3)2(bpt)2.2CH3OH]n and two-dimensional network [Mn(NCS)2(bpt)3.H2O]n, Inorg. Chimi. Acta ,2002 ,332:216-222
25. Yongli Wei, Yu Zhu, Yinglin Song, Hongwei Hou, Yaoting Fan, A novel inorganic-organic tetragonal prism supramolecular compound [Fe9NCS]6][Hbpy0(H2bpy0(bpy)): crystal structure and non-linear optical properties, Inorg. Chem. Commun., 2002, 5: 166-170
26.Hongwei Hou, Xiangru Meng Yinglin Song, Yaoting Fan, Yu Zhu Hujie Lu et al.,Two-dimentionrhombohedrqal grid coordination popymers [M(bbbt)2(NCS)2]n (M=Co,or Cd; bbbt=1,1’-(1,4butanediyl)bis -1H-benzo triazole):synthesis,crystal structures,and third-order nonlinear optical properties,Inorg. Chem.,2002,41,4068-4075
27.Hongwei Hou Yongli Wei Yinglin Song Yu Zhu Linke Li and Yaoting Fan, Two novel two-dimensional double-sheet layered manganese(Ⅱ) coordination polymers:synthesis,crystal structures and third-order nonlinear optical properties,J.Mater.Chem.,2002,12,838-843
28.Gang Li, Hongwei Hou, Yu Zhu, Xiangru Meng, Liwei Mi, Yaoting Fan,Synthesis and crystal structure of a novel zinc(II) coordination polymer with mixed ferrocenyl diketone and bipyridine ligand,Inorg. Chem. Commun., 2002, 5(11), 929-932
29.Huijie Lu Yaoting Fan* Yangjie Wu et al.,Tripod lipophilic ionophores:Synteses,Cation binding and transport through liquid membranes,Polyhedron,2001,20:3281-3286,
30. Huijie Lu Yaoting Fan* Mingcai Yi Hongwei Hou ,Tripod-like compounds: syntheses of tris(ρor ο-amino phenoxymethyl)-propane, tris(ρor ο-amino amine phenoxymethyl)amine,and their schiff base or salicyl derivatives,Syn. Commun.,2001,31(10):1531-1540
31. Hongwei Hou Yaoting Fan Linping Zhang Chenxia Du Yu Zhu, Self-assembly of new 4,4`-bipyridyl-based building block with Cd and Co cations:synthesis and crystal structrures of 1- and 2-D coordination polymers,Inorg. Chemi. Commun.,2001,4:168-172.
32. Hongwei Hou*, Yongli Wei, Yaoting Fan, Chenxia Du, Yunyin Niu, Xinquan Xin, Third-order nonlinear optical properties of coordination polymers and crystal structure of network [Mn(SO4)(4,4_-bpy) (H2O)2]n, Inorg. Chimi. Acta, 2001,319,212?C218
33.Hongwei Hou*, Yinglin Song, Yaoting Fan, Linping Zhang, Chenxia Du,Yu Zhu, A novel coordination polymer [Co(NCS)2(bpms)2]n(bpms=1,2-bis(4-pyridylmethyl)disulfenyl): synthesis, crystalstructure and third-order nonlinear optical properties, Inorg. Chimi. Acta, 2001 316,140?C144
34.Yun yin Niu, Hongwei Hou,Yongli Wei, Yaoting Fan, Yu Zhu, ChenXia Du, Xin quan Xin, A linear
piperazine-pyridine ligand and its Hg coordination polymer,Inorg.Chem.Commun.,2001,4: 358
35. Linke Li, Bingyi Chen, Yinglin Song, Gang Li, Hongwei Houa,*, Yaoting Fan, Liwei Mi, Synthesis, crystal structure and third-order nonlinear optical properties of a novel coordination polymer [Cd(en)(NO3)2(4,4-bpy)]n containing three kinds of ligands, Inorg. Chimi. Acta, 2003, 344:95-101
36. Yaoting Fan Huijie Lu Hongwei Hou hengmin Zhou Linping Zhang et al., Structures of copper(1)and zinc(II)complexes with N,N`-bis(2-pyridinyl)thiourea(BET),J.Coord. Chem.,2000,50:65-72。
37. Hongwei Hou, How Ghee Ang, Siau Gek Ang, Yaoting Fan, Michael K M Low et al., Synthesis and nonlinear optical absorptive and refractive properties of several novel nest-shaped clusters,and crystal structuresof [MoI(bPy)2][MoS3Cu3I2(bPy)]and [MoS3Cu3I(Phen)2],Inorgan. Chim. Acta,2000,299:147-154.
38. Hongwei Hou Yaoting Fan How Ghee Ang Michael K M Low and Wei Li, Large nonlinear optical absorption and self-defocusing effects of cluster [MoS4Cu4I2(py)6],Indian J.Chem.,2000,39A:534-536.
39. Hongwei Hou,* Yongli Wei, Yinglin Song, Liwei Mi,,Mingsheng Tang, Linke Li, and Yaoting Fan,Metal Ions Play Different Roles in the Third-Order Nonlinear Optical Properties of d10 Metal?COrganic Clusters,Angew. Chem. Int. Ed., 2005, 44, 6067 ?C6074
40. 娄新华,朱玉,高辉,朱爱新, 樊耀亭*,侯红卫,卢会杰,一个新的噻二唑衍生物与锰的二维聚合物的合成与晶体结构,无机化学学报,2005,21(5):716-724
41. 杏艳,赵金安,樊耀亭*, 侯红卫,含纤维素类生物质的生物制氢研究,太阳能学报,2006年5月
42. 樊耀亭* 李晨林 赖俊吉 侯红卫,天然厌氧微生物氢发酵生产生物制氢的研究,中国环境科学, 2002,22(4):370-374 (中文SCI,联系人)
43. 樊耀亭* 廖新成 卢会杰 侯红卫,,有机废弃物氢发酵生产制氢的研究,环境科学 ,2003,24(3):132-135 (SCI,联系人) |
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