【龚俊芳】郑州大学化学与分子工程学院研究生导师介绍

信息发布

　　龚军芳，博士、教授，河南省教育厅学术技术带头人。主要从事金属有机化学研究，近年来主持完成教育部留学回国人员科研启动费、河南省自然科学基金、国家自然科学基金等项目；目前主持河南省高校科技创新人才基金等项目。先后在Adv. Synth. Catal.; J. Org. Chem.; Organometallics; Dalton Trans.; Tetrahedron Lett.; J. Mol. Catal. A: Chem.等国内外期刊上发表学术论文60多篇，参与翻译、编写著作3部。获得2008年度宝钢优秀教师奖、河南省教育系统2010教学技能竞赛一等奖并获“河南省教学标兵”称号。

　　学习经历：

　　1992年获得南开大学理学学士学位，

　　1995年获得南开大学理学硕士学位，

　　1998年中国科学院化学研究所毕业，获得博士学位。

　　研究工作经历：

　　1999/10–2001/09  郑州大学化学系博士后

　　2001/10–2003/02  法国巴黎国家高等化学学校 (ENSCP)博士后

　　2003年–至今  郑州大学化学与分子工程学院(原化学系)工作

　　联系方式：  邮箱：gongjf@zzu.edu.cn

　　研究方向：金属有机化学。过渡金属催化的反应在现代有机合成中有着举足轻重的地位，所得到的产物是合成许多药物、天然产物及功能性材料等的关键中间体，具有重要的应用价值。作为一类独特的金属有机化合物，钳形金属化合物(pincer metal complexes)已被用于化学键的活化、发光材料、超分子化学、分子识别等领域，特别是研究发现，该类化合物也是多种催化反应的有效催化剂、在反应中表现出高的催化活性或立体选择性。近年来，我们对钳形金属化合物的合成及其在催化反应中的应用进行了研究，包括：利用廉价易得的原料、通过芳环的C-H键活化方法，合成得到了多种类型的非手性和手性钳形金属化合物，例如：PCP钳形钯化合物、PCN钳形钯和镍化合物、双(咪唑啉)NCN钳形钯、铂、镍、铑和铱化合物、NCN'钳形钯化合物、CNN'钳形钯和钌化合物等。非手性的钳形钯化合物被用于催化Suzuki、Sonogashira、醛的烯丙基化以及醛、胺和烯丙基锡的三组分反应等；钌化合物被用于酮的氢转移反应；手性的钳形钯化合物被用于催化不对称Suzuki反应、醛、N-磺酰亚胺或靛红与烯丙基锡的不对称加成反应、二芳基膦烷与a,β-不饱和酮的不对称加成反应等；铂化合物被用于吲哚与硝基烯烃的不对称傅-克烷基化反应；镍化合物被用于Suzuki和Michael加成等反应；铑化合物被用于三氟丙酮酸酯与端基炔的不对称炔基化反应、醛的烯丙基化以及三氟丙酮酸酯的羰基-烯反应等，均取得了良好的催化效果。

　　承担科研项目

　　1. 2010.1－2012.12 “混合给体钳形镍化合物的合成、结构及其在催化反应中的应用”  编号20972141  国家自然科学基金资助项目2. 2012.1－2014.12 “手性钳形钯化合物催化剂的合成与应用研究”  编号2012HASTIT003  河南省高校科技创新人才支持计划资助项目

　　3. 2009.1－2012.12 “非对称三齿配位钯化合物的催化性能研究” 编号102101210200   河南省科技攻关重大项目

　　4. 2010.1－2012.12 “含氮杂环卡宾的钯和镍化合物的合成与催化性能研究”  编号2010GGJS-015 河南省高等学校青年骨干教师资助计划

　　5. 2006.01-2007.12 “新型氮磷配体的合成及其在催化反应中的应用研究”  编号0611012100  河南省自然科学基金

　　6. 2004.01-2005.12 “多取代四氢吡喃的立体选择性合成、新型二茂铁衍生物的合成及其应用”  教育部留学回国人员科研启动基金

　　部分代表论文

　　Xin-Qi Hao, Yong-Wei Zhao, Jing-Jing Yang, Jun-Long Niu, Jun-Fang Gong*, Mao-Ping Song*. “Enantioselective Hydrophosphination of Enones with Diphenylphosphine Catalyzed by Bis(imidazoline) NCN Pincer Palladium(II) Complexes.” Organometallics 2014, 33(7), 1801-1811.

　　http://pubs.acs.org/doi/abs/10.1021/om500144b?source=chemport

　　Zhao Wang, Zheming Sun, Xin-Qi Hao, Jun-Long Niu, Donghui Wei, Tao Tu, Jun-Fang Gong*, Mao-Ping Song*. “Neutral and Cationic NCN Pincer Platinum(II) Complexes with 1,3-Bis(benzimidazol-2'-yl)benzene Ligands: Synthesis, Structures, and Their Photophysical Properties.” Organometallics 2014, 33(7), 1563-1573.http://pubs.acs.org/doi/abs/10.1021/om400946n?source=chemport

　　Tao Wang, Xin-Qi Hao, Juan-Juan Huang, Kai Wang, Jun-Fang Gong*, Mao-Ping Song*. “Chiral CNN Pincer Palladium(II) Complexes with 2-Aryl-6-(Oxazolinyl)pyridine Ligands: Synthesis, Characterization, and Application to Enantioselective Allylation of Isatins and Suzuki-Miyaura Coupling Reaction.” Organometallics 2014, 33(1), 194-205.

　　http://pubs.acs.org/doi/abs/10.1021/om400945d?source=chemport

　　Tao Wang, Xin-Qi Hao, Juan-Juan Huang, Jun-Long Niu, Jun-Fang Gong*, Mao-Ping Song*. “Chiral Bis(imidazolinyl)phenyl NCN Pincer Rhodium(III) Catalysts for Enantioselective Allylation of Aldehydes and Carbonyl-Ene Reaction of Trifluoropyruvates.” J. Org. Chem. 2013, 78(17), 8712-8721.

　　http://pubs.acs.org/doi/abs/10.1021/jo4014194?source=chemport

　　Tao Wang, Jun-Long Niu, Shuang-Liang Liu, Juan-Juan Huang, Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Rhodium(III) Complexes with Bis(imidazolinyl)phenyl Ligands: Synthesis and Enantioselective Catalytic Alkynylation of Trifluoropyruvates with Terminal Alkynes.” Adv. Synth. Catal. 2013, 355(5), 927-937. (Highlighted by Synfacts 2013, 9(6), 0636)http://onlinelibrary.wiley.com/doi/10.1002/adsc.201200967/abstract

　　研究专题：郝新奇, 牛俊龙, 赵雪梅, 龚军芳*, 宋毛平*. “第VIII族钳形金属催化剂的研究进展.” 有机化学 2013, 33(4), 663-674.

　　http://sioc-journal.cn/Jwk_yjhx/CN/abstract/abstract341980.shtml

　　Xin-Qi Hao, Yan-Xiao Xu, Ming-Jun Yang, Li Wang, Jun-Long Niu, Jun-Fang Gong*, Mao-Ping Song*. “A Cationic NCN Pincer Platinum(II) Aquo Complex with a Bis(imidazolinyl) phenyl Ligand: Studies toward its Synthesis and Asymmetric Friedel?Crafts Alkylation of Indoles with Nitroalkenes.” Organometallics 2012, 31(3), 835-846.http://pubs.acs.org/doi/abs/10.1021/om200714z?source=chemport

　　Ming-Jun Yang, Yan-Jing Liu, Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes with Aryl-Based Aminophosphine-Imidazoline Ligands: Synthesis via Aryl C-H Activation, and Asymmetric Addition of Diarylphosphines to Enones.” Organometallics 2011, 30(14), 3793-3803. http://pubs.acs.org/doi/abs/10.1021/om200350h?source=chemport

　　Invited Perspective: Jun-Long Niu, Xin-Qi Hao, Jun-Fang Gong*, Mao-Ping Song*. “Symmetrical and unsymmetrical pincer complexes with group 10 metals: Synthesis via aryl C–H activation and some catalytic applications.” Dalton Trans. 2011, 40(19), 5135-5150.http://pubs.rsc.org/en/Content/ArticleLanding/2011/DT/c0dt01439g#!divAbstract

　　Tao Wang, Xin-Qi Hao, Xiao-Xue Zhang, Jun-Fang Gong*, Mao-Ping Song*. “Synthesis, structure and catalytic properties of CNN pincer palladium(II) and ruthenium(II) complexes with N-substituted-2-aminomethyl-6-phenyl pyridines.” Dalton Trans. 2011, 40(35), 8964-8976. (封面文章)

　　http://pubs.rsc.org/en/Content/ArticleLanding/2011/DT/c1dt10331h#!divAbstract

　　Dan-Dan Shao, Jun-Long Niu, Xin-Qi Hao, Jun-Fang Gong*, Mao-Ping Song*. “Neutral and cationic chiral NCN pincer nickel(II) complexes with 1,3-bis(2'-imidazolinyl) benzenes: synthesis and characterization.” Dalton Trans. 2011, 40(35), 9012-9019.http://pubs.rsc.org/en/content/articlelanding/2011/DT/c1dt10329f#!divAbstract

　　Ben-Shang Zhang, Wei Wang, Dan-Dan Shao, Xin-Qi Hao, Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes of (Imidazolinyl)aryl Phosphinite Ligands: Synthesis via Ligand C-H Activation, Crystal Structures and Catalytic Studies.” Organometallics 2010, 29(11), 2579-2587.http://pubs.acs.org/doi/abs/10.1021/om100232n?source=chemport

　　Jun-Long Niu, Qing-Tao Chen, Xin-Qi Hao, Qing-Xiang Zhao, Jun-Fang Gong*, Mao-Ping Song*. “Diphenylprolinol-derived Symmetrical and Unsymmetrical Chiral Pincer Palladium(II) and Nickel(II) Complexes: Synthesis via One-Pot Phosphorylation/metalation Reaction and C-H Activation.” Organometallics 2010, 29(9), 2148-2156.http://pubs.acs.org/doi/abs/10.1021/om100234q?source=chemport

　　Li-Yuan Wu, Xin-Qi Hao, Yan-Xiao Xu, Min-Qiang Jia, Ya-Nan Wang, Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Pt(II) and Pd(II) Complexes with 1,3-Bis(2'-imidazolinyl)benzene: Synthesis via Direct Metalation, Characterization, and Catalytic Activity in the Friedel-Crafts Alkylation Reaction.” Organometallics 2009, 28(12), 3369-3380.http://pubs.acs.org/doi/abs/10.1021/om801005j?source=chemport

　　Jun-Fang Gong, Yan-Hui Zhang, Mao-Ping Song*, Chen Xu. “New PCN and PCP Pincer Palladium(II) Complexes: Convenient Synthesis via Facile One-pot Phosphorylation/Palladation Reaction and Structural Characterization.” Organometallics 2007, 26(25), 6487-6492.http://pubs.acs.org/doi/abs/10.1021/om7008364?source=chemport

　　An-Ting Hou, Yan-Jing Liu, Xin-Qi Hao, Jun-Fang Gong*, Mao-Ping Song*. “Synthesis and Characterization of new (pyrazolyl)aryl phosphinite PCN pincer palladium(II) complexes.” J. Organomet. Chem. 2011, 696(15-16), 2857-2862.http://www.sciencedirect.com/science/article/pii/S0022328X11003093

　　Xin-Qi Hao, Ya-Nan Wang, Jun-Rui Liu, Kun-Lun Wang, Jun-Fang Gong,* Mao-Ping Song*. “Unsymmetrical, oxazolinyl-containing achiral and chiral NCN pincer ligand precursors and their complexes with palladium(II).” J. Organomet. Chem. 2010, 695(1), 82-89.http://www.sciencedirect.com/science/article/pii/S0022328X09006342

　　Ben-Shang Zhang, Chao Wang, Jun-Fang Gong*, Mao-Ping Song*. “Facile synthesis of achiral and chiral PCN pincer palladium(II) complexes and their application in the Suzuki and copper-free Sonogashira cross-coupling reactions.” J. Organomet. Chem. 2009, 694(16), 2555-2561.http://www.sciencedirect.com/science/article/pii/S0022328X09002484

　　Xin-Qi Hao, Jun-Fang Gong*, Chen-Xia Du, Li-Yuan Wu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and photoluminescent properties of platinum complexes with novel bis(imidazoline) pincer ligands.” Tetrahedron Lett. 2006, 47(29), 5033-5036.http://www.sciencedirect.com/science/article/pii/S0040403906010306#

　　Chen Xu, Jun-Fang Gong*, Su-Fang Yue, Yu Zhu, Yang-Jie Wu*. “Tricyclohexylphosphine- cyclopalladated ferrocenylimine complexes: synthesis, crystal structures and application in Suzuki and Heck reactions.” Dalton Trans. 2006, (39), 4730-4739.Chen Xu, Jun-Fang Gong*, Tao Guo, Yan-Hui Zhang, Yang-Jie Wu*. “Cyclopalladated ferrocenylimine complexes with dicyclohexylphosphinobiphenyl ligands: Synthesis, crystal structures and their use as highly efficient catalysts for Suzuki reaction of aryl chlorides.” J. Mol. Catal. A: Chem. 2008, 279(1), 69-76.Chen Xu, Jun-Fang Gong*, Yang-Jie Wu*. “Amination of aryl chlorides in water catalyzed by cyclopalladated ferrocenylimine complexes with commercially available monophosphinobiaryl ligands.” Tetrahedron Lett. 2007, 48(9), 1619-1623.Jun-Fang Gong*, Xin-Heng Fan, Chen Xu, Jin-Lei Li, Yang-Jie Wu*, Mao-Ping Song. “New cycloplatinated complexes with 2-arylimidazolines: synthesis, crystal structures and photophysical properties.” J. Organomet. Chem. 2007, 692(10), 2006-1013. Junfang Gong, Guangyu Liu, Chenxia Du, Yu Zhu, Yangjie Wu*. “Efficient Suzuki coupling of aryl chlorides catalyzed by tricyclohexylphosphine adducts of cyclopalladated ferrocenylimines.” J. Organomet. Chem. 2005, 690(17), 3963-3969.Kai Xu, Xin-Qi Hao, Jun-Fang Gong*, Mao-Ping Song*, and Yang-Jie Wu. “Room Temperature Suzuki Reactions in Aqueous Media under Air by Palladium(II) Complexes with Pyrazole Derived Ligands.” Aust. J. Chem. 2010, 63(2), 315-320.Chen Xu, Jun-Fang Gong*, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis, Characterization and Crystal Structures of Three cis/trans Pyridine-Cyclopalladated Ferrocenylimine Complexes, and Their Catalysis in Suzuki Reactions.” Aust. J. Chem. 2007, 60(3), 190-195.Xin-Qi Hao, Fang Liu, Bi Zhang, Mei-Ling Jiang, Jun-Fang Gong*, Mao-Ping Song*. “Cyclopalladated complexes of 2-(m-nitrophenyl)imidazolines: synthesis, characterization and catalytic activity in the Suzuki reaction under mild conditions.” Transition Met. Chem. 2010, 35(3), 271-277. Chen Xu, Jun-Fang Gong*, Mao-Ping Song, Yang-Jie Wu*. “Catalysis of the coupling reaction of aryl chlorides with bis(pinacolato)diboron by tricyclohexylphosphine-cyclopalladated ferrocenylimine complexes.” Transition Met. Chem. 2009, 34(2), 175-179.Jun-Fang Gong*, Chen Xu, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis, characterization and crystal structures of two cis/trans pyridine-cyclopalladated ferrocenylimine complexes.” Transit. Metal Chem. 2007, 32(7), 1000-1004.Xin-Qi Hao, Jun-Fang Gong*, Wen-Tao Song, Yang-Jie Wu, Mao-Ping Song*. “Synthesis and crystal structures of mono-, bis- as well as tris-mercurated complexes with ferrocenylazines.” Inorg. Chem. Commun. 2007, 10(3), 371-375.

　　GONG Jun-fang*, ZHANG Yan-hui, FAN Xin-heng, WANG Da-wei, SONG Mao-ping, WU Yang-jie. “Synthesis, Structural Characterization of Ferrocenyl Iminophosphines and Amidophosphines as Well as Their Application in the Suzuki Reaction.” Chem. Res. Chinese U. 2007, 23(6), 683-687.Jun-Fang Gong*, Da-Wei Wang, Yan-Hui Zhang, Yu Zhu, Yang-Jie Wu*. “Synthesis and Structural Characterization of Mercury(II) Complexes with a Novel Ferrocenyliminophosphine.” Inorg. Chim. Acta 2006, 359(7), 2115-2120.Chen Xu, Jun-Fang Gong, Yan-Hui Zhang, Yu Zhu, Chen-Xia Du, Yang-Jie Wu*. “Synthesis, characterization and crystal structures of a novel 1,1’-bisferrocenylimine and its monocyclopalladated derivative.” Inorg. Chem. Commun. 2006, 9(5), 456-459.Ling-Zhi Du, Jun-Fang Gong*, Chen Xu, Yu Zhu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis and structures of novel diastereomeric cyclopalladated ferrocenylimines derived from chiral b-amino alcohols.” Inorg. Chem. Commun. 2006, 9(4), 410-414.Ling-Zhi Du, Jun-Fang Gong*, Yu Zhu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and the crystal structures of novel achiral and chiral a-ferrocenyl a-aminophosphine oxides.” Inorg. Chem. Commun. 2006, 9(5), 529-532.Junfang Gong, Guangyu Liu, Yu Zhu, Chenxia Du, Maoping Song, Yangjie Wu*. “Synthesis, Characterization and Catalytic Activity in Suzuki Reaction of Cyclopalladated Ferrocenylimine Triphenylphosphine complexes.” Chem. J. Chin. Univ. 2006, 27(7), 1266-1271.Junfang Gong, Chen Xu, Yangjie Wu*. “Transition-Metal Catalyzed α-Arylation of Carbonyl Derivatives and Compounds with Acidic Hydrogen.” Progress in Chem. 2006, 18(6), 752-760.Junfang Gong, Eric Bonfand, Eric Brown, Gilles Dujardin*, Véronique Michelet*, Jean-Pierre Genêt. “Remarkable stereocontrol in the synthesis of 1,2,3,5-tetrasubstituted tetrahydropyrans via an asymmetric heterocycloaddition of a ketone-derived enol ether. ” Tetrahedron Lett. 2003, 44(10), 2141-2144.

　　Junfang Gong, Qinghua Fan and Dazhi Jiang*. “Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride.” J. Mol. Catal. A: Chem. 1999, 147(1-2), 113-124.

　　参与翻译、编写的著作

　　1. 宋毛平, 毛璞, 廖新成, 张雁冰, 龚军芳. 有机立体化学导论(译著, 国外名校名著系列), 化学工业出版社, 2007.1

　　2. 龚军芳. 傅瑞德尔-克拉夫兹反应 (现代有机反应第5卷 金属催化反应  胡跃飞 林国强主编)，化学工业出版社，2008.12

　　3. 龚军芳, 宋毛平. 玉尾-熊田-弗莱明立体选择性羟基化反应 (现代有机反应第8卷 碳-杂原子键参与的反应II  胡跃飞 林国强主编)，化学工业出版社， 2013.1